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Professor Lee Ji-hoon ’s Research Team Develops Hybrid Mn-Doped NiBP Electrocatalyst for Low-Cost

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·         Professor Lee Ji-hoon (Department of Electronic Engineering)s Research Team Develops Hybrid Mn-Doped NiBP Electrocatalyst for Low-Cost, High-Efficiency Green Hydrogen Production

Views 87 | Created on 2025.01.02 | Modified on 2025.01.02 | Public Relations Team

·         Professor Lee Ji-hoon (Department of Electronic Engineering)’s Research Team

Develops Hybrid Mn-Doped NiBP Electrocatalyst for Low-Cost, High-Efficiency Green Hydrogen Production

- Development of a Novel Mn-Doped NiBP Microsphere Electrocatalyst Using Combined Hydrothermal and Electrochemical Deposition Methods -

- Published in the Prestigious Academic Journal “International Journal of Hydrogen Energy” (IF: 8.1) by Elsevier -

 

Professor Lee Ji-hoon (Department of Electronic Engineering) and his research team, in collaboration with first author Sumiya (Researcher, Department of Electronic Engineering), have successfully developed the world’s first hybrid “Mn-doped NiBP microsphere” electrocatalyst. This innovative structure, designed for low-cost, high-efficiency green hydrogen production, was achieved by combining hydrothermal and electrochemical deposition techniques.

 

The Mn/NiBP microspheres exhibited low overpotentials of 62 mV and 250 mV for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), respectively, at 50 mA/cm² in 1M KOH. The Mn/NiBP (-) || Mn/NiBP (
+) two-electrode system demonstrated a low cell voltage of 3.07 V at 2000 mA/cm
² in 1M KOH, outperforming the benchmark reference Pt/C (-) || RuO (+) electrodes. Additionally, the Pt/C (-) || Mn/NiBP (+) hybrid system exhibited an ultra-low cell voltage of 2.82 V at 2000 mA/cm² in 1M KOH, demonstrating the electrocatalytic robustness and strong corrosion resistance of the Mn/NiBP microspheres. Doping Mn into NiBP microspheres has been shown to accelerate charge transfer and enhance electrocatalytic activity, making it a cost-effective electrocatalyst candidate for industrial applications.

 Schematic illustration of the novel “Mn-doped NiBP microsphere” electrocatalyst developed using a hybrid Mn doping method by combining hydrothermal deposition and electrochemical deposition techniques (International Journal of Hydrogen Energy, 2024) 

 

Schematic illustration of the novel “Mn-doped NiBP microsphere” electrocatalyst developed using a hybrid Mn doping method by combining hydrothermal deposition and electrochemical deposition techniques (International Journal of Hydrogen Energy, 2024)

 

The research team consists of Sumiya Akter Dristy (Ph.D. candidate, Kwangwoon University, first author), Shusen Lin (Researcher, Key Research Institute, Kwangwoon University), Md Ahasan Habib (Ph.D. candidate, Kwangwoon University), Mehedi Hasan Joni (Ph.D. candidate, Kwangwoon University), Rutuja Mandavkar (Ph.D. candidate, Kwangwoon University), and Lee Ji-hoon (Professor, Kwangwoon University, corresponding author). The study was conducted solely by Kwangwoon University. Researcher Sumiya Akter Dristy joined the integrated master's and Ph.D. program in the Department of Electronic Engineering at Kwangwoon University in 2023 and is currently in her second year of the program. Researcher Sumiya has actively participated in studies on quantum and nanostructures as well as materials science, publishing multiple research papers to date. Researcher Sumiya expressed her ambition to continue producing outstanding research outcomes and to further her studies at leading research institutions in the future.

This research was conducted with the support of the Brain Korea 21 Plus (BK-21) program, the Key Research Institute program―both funded by the National Research Foundation of Korea and the Ministry of Education―and Kwangwoon University. The findings were published in the December 2024 issue of the scientific journal International Journal of Hydrogen Energy (JCR IF: 8.1) under the title "Manganese doped NiBP: A promising electrocatalyst for sustainable hydrogen production at high-current-density (HCD)." * Publication Web link: https://doi.org/10.1016/j.ijhydene.2024.11.283

Meanwhile, Professor Lee Ji-hoon’s research team is currently working on the development of high-efficiency, high-performance energy materials, various metasurface-based nanomaterials, and optoelectronic device and system technologies. To date, the team has published over 180 papers in top-ranked SCI JCR journals. Professor Lee Ji-hoon serves as an Assistant Editor and Editorial Board member for SCI journals published by globally renowned publishers, as well as a Guest Editor for various SCI-grade international journals. He also holds various committee and organizer roles in international conferences. For over 20 years, he has also served as a reviewer for more than 30 SCI journals, including Advanced Materials (IF 27.4), Nano Energy (IF 16.8), and Advanced Functional Materials (IF 18.5).

 

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